Free radicals coming from environmental stressors like the sun's UV rays can really cause a lot of problems. It's actually believed that free radicals are the reason behind a lot of premature aging, skin damage and even your risk of developing cancer.

Protect Your Skin with Antioxidant-rich Vitamins 

By incorporating more antioxidants into your diet and skin-care regimen, though, you can prevent free radicals from damaging the cells in your body and its largest organ, your skin.

You can, for example, apply Vitamin A topically to help neutralize a lot of the free radical damage that can occur by being out unprotected in the sun too long. By extension, taking Vitamin A and neutralizing free radical damage can help remove or significantly reverse brown spots, wrinkles or unsightly sagging.

Healthy Skin, Healthy Body 

  It's often been said that your skin is a good indicator of the overall health of your body. And the good news is that there are a few anti-aging vitamins and minerals designed to prevent free radicals from causing your skin to develop wrinkles or discoloration. The mineral Selenium, for instance, has been shown to increase skin elasticity and reduce rough skin and UV damage.

http://www.webmd.com/beauty/aging/myth-vs-reality-on-anti-aging-vitamins

Certain vitamins can also keep your skin feeling supple and looking vibrant. Eating a diet high in Vitamin A and Vitamin C is obviously important for maintaining eye health and mitigating free radical damage, but it can also help you look great.

The thing to bear in mind is that only a fraction of these vitamins are used by the body to directly improve the luster of your skin, according to leading dermatologists. What you need is a combination of vitamins through the foods you eat and supplements you take and vitamins in your skin-care regimen applied topically so that your cells don't encounter free radical damage and your skin continues to look great.

Here's what to take:

Vitamin A 

You may have heard that there's a lot of Vitamin A in carrots and sweet potatoes…well, that's about half true. What's actually in those fruits is a red-orange pigment called beta-Carotene, which is a precursor to Vitamin A and very important to have in your diet.

Retinol, found in many topical skin-care formulas, and beta-Carotene are things that your body knows how to turn into Vitamin A to keep your skin and your whole body healthy and radiant. In fact, a lot of night creams have retinol or retinoic acid in them to help combat wrinkles and do away with brown spots.

In addition to giving your body the building blocks to fight wrinkles and brown spots, Vitamin A can also neutralize free radical damage caused by the sun and smooth out the roughness that your skin can develop over time.

A lot of people also use Vitamin A in topical creams to reduce the appearance of crow's feet or darkness under the eyes as well.

Vitamin K

Vitamin K can work to mitigate the dark circles under your eyes; these dark circles are thought to be caused by tiny capillaries leaking blood into your skin.

Fat-soluble Vitamin K can actually come in and prevent a lot of this blood clotting and, therefore, reduce the presence of dark circles under your eyes.

Vitamin C 

The chemist Linus Pauling actually made a name for himself after winning the Nobel Prize in Chemistry for touting the benefits of Vitamin C for curing everything from the common cold to cancer.

There's actually some truth to a lot of these claims since Vitamin C is an antioxidant found naturally in many citrus fruits like oranges, grapefruits and tangerines…and also in a lot of skin-care formulas.

Vitamin C, sometimes called ascorbic acid, is a potent antioxidant that can help fight against oxidation stress found in the environment in the form of the sun's harmful UV rays, cigarette smoke and other pollutants that we're exposed to on a daily basis.

Dermatologists recommend that you use Vitamin C in your skin moisturizer as an all-encompassing anti-aging substance to combat rough skin, brown spots, sagging and wrinkles that accumulate as we age.

Vitamin E 

Vitamin E sometimes appears under the names tocopherol or tocotrienol on the ingredients list to a lot of moisturizers. A fat-soluble vitamin and potent antioxidant in its own right, Vitamin E can treat cracked and dry skin.

Vitamin E is renowned for its ability to moisturize the skin and aiding the skin in retaining more of its natural moisturizing substances. That's part of the reason that Vitamin E usually comprises one percent or more of the ingredients list of the most popular sunscreens, after-sun products and moisturizers.

The other reason is that Vitamin E works to quell the dryness that can set in after you've been out in the sun while enhancing your skin's natural UV defenses against further damage.

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